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          3-Butenylmagnesium bromide 3-丁烯基溴化鎂

          規格: 0.5 M solution in THF, SpcSeal
          CAS: 7103-09-5
          産品編号: H53937
          MDL: MFCD00209554
          品牌: INFI
          Chemical Name3-Butenylmagnesium bromide
          CAS Number7103-09-5
          EC Number250-023-7
          Beilstein Registry Number2384789
          MDL NumberMFCD00209554
          PubChem Substance ID24866263
          Synonym 3-丁烯基溴化鎂 3-丁烯溴化鎂 3-丁烯基溴化鎂 溶液
          Chemical Name Translation3-丁烯基溴化鎂
          LabNetwork Molecule IDLN01314450
          GHS Symbol
          Signal word Danger
          WGK Germany3
          Safety Statements
          • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸後,立即用大量水沖洗并征求醫生意見;
          • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适當的防護服、手套和眼睛/面保護;
          • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 發生事故時或感覺不适時,立即求醫(可能時出示标簽);
          • S16 Keep away from sources of ignition - No smoking 遠離火源,禁止吸煙;
          • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火時使用(指明具體的消防器材種類,如果用水增加危險,注明“禁止用水”
          • S36/37 Wear suitable protective clothing and gloves 穿戴适當的防護服和手套;
            Risk Statements
            • R11 Highly flammable 非常易燃
            • R19 May form explosive peroxides 可能生成易爆的過氧化物質
            • R36/37/38 Irritating to eyes, respiratory system and skin 對眼睛、呼吸系統和皮膚有刺激性
            • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水劇烈反應,釋放出高度可燃氣體
            • R40 Limited evidence of a carcinogenic effect 有限證據表明其緻癌作用
            • R34 Causes burns 會導緻灼傷
              Precautionary statements
              • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 遠離熱源/火花/明火/熱的表面。——禁止吸煙。
              • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
              • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。
              • P305+P351+P338
              • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 遠離任何與水接觸的可能,因爲會劇烈反應可能産生閃火。
              • P422 Store contents under… 存儲目錄在…之下。
              • P231+P232
              • P370+P378
              • P402+P404
              • P403+P235
                Hazard statements
                • H314 Causes severe skin burns and eye damage 導緻嚴重的皮膚灼傷和眼睛損傷
                • H351 Suspected of causing cancer 懷疑緻癌
                • H260 In contact with water releases flammable gases which may ignite spontaneously 與水接觸時釋放可燃氣體,可自燃。
                • H225 Highly flammable liquid and vapour 高度易燃液體和蒸氣
                • H335 May cause respiratory irritation 可能導緻呼吸道刺激
                • H302 Harmful if swallowed 吞食有害
                  Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
                  Hazard Codes F,Xn 4.3
                  UN Number
                  Storage condition 密封充氩保存
                  Packing Group
                • 從L-酒石酸合成(–)-muricatacin中,3-丁烯溴化鎂用于一種非對映體選擇性的關鍵步驟,也用于钌催化劑催化下的成環反應。
                • 7103-09-5 H53937 3-Butenylmagnesium bromide


                  Mol. FormulaH2C=CHCH2CH2MgBr
                  Mol. Weight159.31
                  Density0.937 g/mL at 25 °C
                  Boiling Point65 °C
                  Flash Point-30 ºC
                  Density0.937 g/mL at 25 °C
                  Mol. FormulaH2C=CHCH2CH2MgBr
                  Mol. Weight159.31